UWEC CERCA 2025

Architectural coatings are categorized as either solvent-based or water-based, with the latter gaining popularity due to their lower volatile organic compound (VOC) content and simplified manufacturing process. However, their performance can be limited compared to oil-based alternatives. To address these challenges, dispersants are incorporated to enhance stability and prevent titanium dioxide (TiO₂) particle aggregation, the primary pigment in the majority of architectural coatings. Our research investigates the structure-property relations of stimuli responsive polyethylene glycol:poly(2-(dimethylamino)ethyl methacrylate) [PEG:PDMAEMA] block copolymers and specifically their application as an eco-friendly TiO₂ dispersant in water-based coatings. These block copolymers were synthesized via ARGET ATRP (Activators ReGenerated by Electron Transfer - Atom Transfer Radical Polymerization), a process which allows for precise control of block length with minimal catalyst use. Various block length ratios were synthesized and characterized, with stress-dependent flow properties analyzed using rheometry and interfacial activity assessed via pendant drop tensiometry. Paint formulation performance was compared to a market standard through Leneta chart and water droplet testing, evaluating opacity, gloss, and resistance to leeching. These findings highlight the potential of incorporating PEG:PDMAEMA polymer dispersants into architectural coatings as a viable alternative to solvent-based coatings while maintaining essential performance properties.